Titanium-based Lead Dioxide Anode
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Titanium-based Lead Dioxide Anode

The Titanium-based Lead Dioxide Anode consists of a titanium substrate coated with a high-purity lead dioxide (PbO₂) layer. This structure combines the corrosion resistance of titanium with the high current efficiency and oxygen evolution potential of PbO₂. It is ideal for demanding electrochemical environments such as copper, nickel, and manganese electrowinning.
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Product Introduction
Corrosion resistant titanium based lead dioxide anode
Advanced PbO₂ Coating on Titanium Substrate for Extended Anode Life

Durable, High-Performance Anode for Acidic Electrolytic Applications

The Titanium-based Lead Dioxide Anode consists of a titanium substrate coated with a high-purity lead dioxide (PbO₂) layer. This structure combines the corrosion resistance of titanium with the high current efficiency and oxygen evolution potential of PbO₂. It is ideal for demanding electrochemical environments such as copper, nickel, and manganese electrowinning.

 

Structure & Coating Composition

 

 

The anode adopts a three-layer composite structure to maximize performance and service life:

  1. Substrate Layer: Grade 1/Grade 2 pure titanium plate/mesh
  2. Intermediate Layer: Conductive tin-antimony oxide layer (improves coating adhesion)
  3. Active Coating Layer: α-PbO₂ + β-PbO₂ dual-phase composite coating
  • α-PbO₂: Provides excellent mechanical strength and adhesion
  • β-PbO₂: Delivers high electrocatalytic activity and current efficiency

Coating Thickness: 50–150 μm (customizable based on application requirements)

 

Key Electrochemical Features

  • High oxygen evolution overpotential (≥1.75 V vs. SHE in 1M H₂SO₄)
  • Low electrical resistivity (≤2×10⁻⁵ Ω·cm)
  • Stable current efficiency (≥94% in copper electrowinning)
  • Excellent dimensional stability (deformation rate <0.1% after 1000 hours operation)
  • Strong resistance to sulfuric acid and heavy metal corrosion

 

 

Titanium Anodes Are Used in Copper EW project 4     Titanium-based Lead Dioxide Anode Plate 1

 

Technical Specifications

 

Item Specification
Substrate Material Grade 1/Grade 2 Titanium
Coating Type α/β Dual-Phase Lead Dioxide
Current Density Range 100–800 A/m²
Recommended Operating Temperature 0–60 °C
Compatible Electrolytes Sulfuric acid, mixed acid, neutral salt solutions
Standard Service Life 8000–15000 hours (under normal operating conditions)
Available Shapes Plate, mesh, tube, rod, custom geometries

 

 

Product Advantages

 

 

  1. High Current Efficiency & Energy Saving
    Low oxygen evolution overpotential reduces cell voltage by 0.15–0.3 V compared with traditional lead anodes, saving about 8–15% of electricity consumption, which brings significant cost savings for long-term operation.
  2. Longer Service Life
    Dense lead dioxide coating has excellent corrosion resistance in sulfuric acid electrolyte, with service life 30–50% longer than conventional lead-silver anodes, reducing replacement frequency and maintenance cost.
  3. Stable Coating Quality
    The coating is firmly bonded to the titanium substrate, not easy to peel off. The uniform coating ensures stable current distribution and consistent electrolysis performance throughout the service cycle.
  4. High Current Density Adaptability
    Can operate stably under higher current density (up to 500 A/m²), which helps increase tankhouse production capacity without increasing cell quantity.
  5. Low Lead Pollution Risk
    Compared with traditional lead alloy anodes, lead dioxide coating has lower dissolution rate, reducing lead ion content in electrolyte and lead pollution risk in cathode copper product.

 

 

Quantifiable Advantages Over Traditional Lead Alloy Anodes

 

 

The advanced materials science behind our Titanium-based Lead Dioxide Anode Plate translates directly into operational superiority and significant cost savings, as demonstrated in the comparison below.

 

Feature
Traditional Lead Alloy Anode
Our Titanium-based PbO₂ Anode
Your Direct Benefit
1. Service Life​
Gradually corrodes over time, typically lasting 2-6 years depending on operating conditions.
Extends service life by a minimum of 50%, often exceeding 100% increase.​ The inert titanium core does not corrode, and the β-PbO₂ layer wears slowly and predictably.
Drastically reduced replacement frequency and costs.​ Minimizes cell downtime for anode changes, increasing overall plant availability.
2. Corrosion Resistance & Anode Slime​
Continuous corrosion leads to the formation of lead-containing sludge (PbO₂, PbSO₄), which contaminates cathodes.
Near-zero corrosion of the substrate.​ The β-PbO₂ surface is highly stable, resulting in virtually no anode slime generation.​
Higher cathode purity (e.g., LME Grade A).​ Reduces cathode scraping, lowers electrolyte purification costs, and minimizes environmental waste handling.
3. Operational Efficiency​
Forms a resistive PbO₂ layer; higher cell voltage is often required over time. Prone to warping.
Maintains a stable, low cell voltage​ due to its high catalytic activity and permanent shape. The titanium substrate is immune to warping.
Estimated 5-10% reduction in energy consumption​ due to lower overpotential for oxygen evolution. Stable spacing ensures consistent current density.
4. Total Cost per Ton of Metal​
Lower upfront cost, but higher long-term costs for energy, sludge management, and anode replacement.
Higher initial investment with a superior ROI.​ Data from commercial operations indicate a minimum 3% reduction in integrated production cost per ton of cathode copper, factoring in energy, maintenance, and purity gains.
Direct improvement to your bottom line.​ Transforms the anode from a consumable into a long-term efficiency asset.
Available Configurations
  • Standard plate sizes: 100×100 mm to 2000×1000 mm
  • Mesh opening: 5×5 mm, 10×10 mm, 15×15 mm
  • Thickness: 1.0 mm, 1.5 mm, 2.0 mm, 3.0 mm
  • Connection methods: Welding, bolted connection, busbar clamping

 

 

Primary Applications
  • High-current-density copper electrowinning tankhouses
  • Modern tankhouses pursuing energy saving and efficiency improvement
  • Copper solvent extraction-electrowinning (SX-EW) projects
  • High-purity cathode copper production lines
  • Old tankhouse anode upgrading and energy-saving renovation

 

Durable titanium lead dioxide anode for electrolysis

 

 

Quality Control & Testing

All anodes undergo strict factory testing before delivery:

  • Coating thickness measurement (eddy current method)
  • Adhesion test (scratch test and thermal shock test)
  • Conductivity and resistivity test
  • Accelerated corrosion test
  • Current distribution uniformity test

 

 
Packaging & Shipping

Massive Production Photo of Titanium Anode

Export Expertise

Experienced with international logistics and documentation, including Certificate of Origin processing.

Reinforced Steel Frame Packaging

Each anode is fixed securely to prevent coating damage during handling or transport.

Optimized Loading

If combined with electrowinning cell purchases, we can load anodes inside the cells to reduce container space and cut freight costs.

Transport Options

Flexible sea, land, or rail delivery based on destination and customer preference.

 

 

FAQ

Q1: What's the difference between this and standard Pb anodes?

A1: Titanium-based PbO₂ anodes offer greater corrosion resistance and a much longer lifespan due to the titanium substrate and optimized coating process.

Q2: Can I request a specific coating type (α-PbO₂ or β-PbO₂)?

A2: Yes, we can produce anodes with either or both forms of PbO₂ coating depending on your application needs.

Q3: Are these anodes suitable for manganese or zinc electrowinning?

A3: Yes, the anodes are applicable for a wide range of acidic electrolytic environments, including manganese, zinc, and copper.

Q4: Do you offer testing samples?

A4: Samples can be provided upon request to verify performance before full-scale orders.

 

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