Titanium-based Lead Dioxide Anode

Advanced PbO₂ Coating on Titanium Substrate for Extended Anode Life
Durable, High-Performance Anode for Acidic Electrolytic Applications
The Titanium-based Lead Dioxide Anode consists of a titanium substrate coated with a high-purity lead dioxide (PbO₂) layer. This structure combines the corrosion resistance of titanium with the high current efficiency and oxygen evolution potential of PbO₂. It is ideal for demanding electrochemical environments such as copper, nickel, and manganese electrowinning.
Structure & Coating Composition
The anode adopts a three-layer composite structure to maximize performance and service life:
- Substrate Layer: Grade 1/Grade 2 pure titanium plate/mesh
- Intermediate Layer: Conductive tin-antimony oxide layer (improves coating adhesion)
- Active Coating Layer: α-PbO₂ + β-PbO₂ dual-phase composite coating
- α-PbO₂: Provides excellent mechanical strength and adhesion
- β-PbO₂: Delivers high electrocatalytic activity and current efficiency
Coating Thickness: 50–150 μm (customizable based on application requirements)
Key Electrochemical Features
- High oxygen evolution overpotential (≥1.75 V vs. SHE in 1M H₂SO₄)
- Low electrical resistivity (≤2×10⁻⁵ Ω·cm)
- Stable current efficiency (≥94% in copper electrowinning)
- Excellent dimensional stability (deformation rate <0.1% after 1000 hours operation)
- Strong resistance to sulfuric acid and heavy metal corrosion

Technical Specifications
| Item | Specification |
|---|---|
| Substrate Material | Grade 1/Grade 2 Titanium |
| Coating Type | α/β Dual-Phase Lead Dioxide |
| Current Density Range | 100–800 A/m² |
| Recommended Operating Temperature | 0–60 °C |
| Compatible Electrolytes | Sulfuric acid, mixed acid, neutral salt solutions |
| Standard Service Life | 8000–15000 hours (under normal operating conditions) |
| Available Shapes | Plate, mesh, tube, rod, custom geometries |
Product Advantages
- High Current Efficiency & Energy Saving
Low oxygen evolution overpotential reduces cell voltage by 0.15–0.3 V compared with traditional lead anodes, saving about 8–15% of electricity consumption, which brings significant cost savings for long-term operation. - Longer Service Life
Dense lead dioxide coating has excellent corrosion resistance in sulfuric acid electrolyte, with service life 30–50% longer than conventional lead-silver anodes, reducing replacement frequency and maintenance cost. - Stable Coating Quality
The coating is firmly bonded to the titanium substrate, not easy to peel off. The uniform coating ensures stable current distribution and consistent electrolysis performance throughout the service cycle. - High Current Density Adaptability
Can operate stably under higher current density (up to 500 A/m²), which helps increase tankhouse production capacity without increasing cell quantity. - Low Lead Pollution Risk
Compared with traditional lead alloy anodes, lead dioxide coating has lower dissolution rate, reducing lead ion content in electrolyte and lead pollution risk in cathode copper product.
Quantifiable Advantages Over Traditional Lead Alloy Anodes
The advanced materials science behind our Titanium-based Lead Dioxide Anode Plate translates directly into operational superiority and significant cost savings, as demonstrated in the comparison below.
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- Standard plate sizes: 100×100 mm to 2000×1000 mm
- Mesh opening: 5×5 mm, 10×10 mm, 15×15 mm
- Thickness: 1.0 mm, 1.5 mm, 2.0 mm, 3.0 mm
- Connection methods: Welding, bolted connection, busbar clamping
- High-current-density copper electrowinning tankhouses
- Modern tankhouses pursuing energy saving and efficiency improvement
- Copper solvent extraction-electrowinning (SX-EW) projects
- High-purity cathode copper production lines
- Old tankhouse anode upgrading and energy-saving renovation

Quality Control & Testing
All anodes undergo strict factory testing before delivery:
- Coating thickness measurement (eddy current method)
- Adhesion test (scratch test and thermal shock test)
- Conductivity and resistivity test
- Accelerated corrosion test
- Current distribution uniformity test
Packaging & Shipping

Export Expertise
Experienced with international logistics and documentation, including Certificate of Origin processing.
Reinforced Steel Frame Packaging
Each anode is fixed securely to prevent coating damage during handling or transport.
Optimized Loading
If combined with electrowinning cell purchases, we can load anodes inside the cells to reduce container space and cut freight costs.
Transport Options
Flexible sea, land, or rail delivery based on destination and customer preference.
FAQ
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